
简介:
郑柏树,男,1978年生,博士,副教授,硕士生导师,现任澳门新葡亰手机版副院长。2011年12月毕业于南京大学配位化学国家重点实验室,首届“唐敖庆化学奖学金”获得者。目前主要从事功能多孔金属有机框架材料(MOFs)的设计合成以及能源环境相关气体吸附存储、催化等性能研究。已主持国家自然科学基金青年项目1项,湖南省自然科学基金等科研、教研项目7项。首次成功将酰胺基、草酰胺基等极性桥连基修饰到孔结构稳定的高比表面MOFs材料中,为定向设计合成新型高性能MOFs储气材料提供了新思路。已在J. Am. Chem. Soc、Chem. Commun.、Inorg. Chem.、Dalton Trans.、Crystal Growth & Design等国际重要学术刊物上发表论文20余篇,被Chem. Soc. Rev.、Coord. Chem. Rev等期刊引用1000余次。参与主编高等教育“十二五”规划教材1部。
联系方式:
Email: zbaishu@163.com
主持的科研或教研项目:
[1] 国家自然科学基金青年项目,酰胺功能基修饰多孔配位聚合物的设计、合成与二氧化碳气体吸附性能研究(21201062),23.0万,2013.01-2015.12
[2] 湖南省自然科学基金青年项目,高孔隙率MOFs的定向构筑与H2、CO2气体吸附性能研究(14JJ3113),4.0万,2014.01-2016.12
[3] 湖南省教育厅科研项目,酰胺基修饰多孔配位聚合物的设计、合成与二氧化碳气体吸附性能研究(12C0115),1.0万,2012.01-2014.12
[4] 南京大学配位化学国家重点实验室开放课题,(3, 12)-连接MOFs的设计合成与H2、CO2气体吸附性能研究(SKLCC1417),3.0万,2014.01-2015.12
[5] 湖南科技大学博士启动基金,高孔隙率多孔配位聚合物的定向构筑及其能源环境相关气体吸附性能研究(E51263),3.0万,2013.01-2015.12
[6] 湖南省普通高等学校教学改革研究项目,制药工程专业人才培养模式改革研究与实践(G21506),2.0万,2016.01-2018.12
[7]企业横向项目,高纯硫酸锰精制技术开发(D11779),65.0万,2017.12-2018.12
[8] 湖南省自然科学基金面上项目,高性能储气脲基MOFs材料的合成与构效关系研究(2018JJ211),5.0万,2018.01-2020.12
发表的主要论文:
[1] B. S. Zheng, J. F. Bai*, J. G. Duan, L. Wojtas and M. J. Zaworotko*, Enhanced CO2binding affinity of a high-uptake rht-type metal-organic framework decorated with acylamide groups, J. Am. Chem. Soc., 2011, 133, 748-751.
[2] B. S. Zheng, Z. Yang, J. F. Bai*, Y. Z. Li and S. H. Li*, High and selective CO2capture by two mesoporous acylamide-functionalized rht-type metal-organic frameworks,Chem. Commun., 2012, 48, 7025-7027.
[3] B. S Zheng, H. T. Liu, Z. X. Wang*, X. Y. Yu*, P. G. Yi and J. F. Bai*, porous NbO-type metal–organic framework with inserted acylamide groups exhibiting highly selective CO2 capture, CrystEngComm, 2013, 16, 3517-3520.
[4] Z. X. Wang, B. S. Zheng*, H. T. Liu, X. Lin, X. Y. Yu, P. G. Yi and R. R. Yun*, High-capacity gas storage by a microporous oxalamide-functionalized NbO-type metal-organic framework, Cryst. Growth Des., 2013, 13, 5001-5006.
[5]B. S. Zheng*, R. R. Yun, J. F. Bai*, Z. Y. Lu, L. T. Du and Y. Z. Li, Expanded porous MOF-505 analogue exhibiting large hydrogen storage capacity and selective carbon dioxide adsorption, Inorg. Chem., 2013, 52, 2823-2829.
[6]Z. X. Wang, B. S. Zheng*, H. T. Liu, P. G. Yi, X. F. Li, X. Y. Yu* and R. R. Yun*, A highly porous 4,4-paddlewheel-connected NbO-type metal-organic framework with a large gas-uptake capacity, Dalton Trans., 2013, 42, 11304-11311.
[7] B. S. Zheng*, X. Lin, Z. X. Wang*, R. R. Yun, Y. P. Fan, M. S. Ding, X. L. Hu and P. G. Yi*, CrystEngComm, 2014, 16, 9586-9589.
[8]L. T. Du, S. L. Yang, L. Xu*, H. H. Min and B. S. Zheng*, Highly selective carbon dioxide uptake by a microporous kgm-pillared metal-organic framework with acylamide groups, CrystEngComm, 2014, 16, 5520-5523.
[9]R. R. Yun*, R. R. Cui, F. J. Qian, X. Y. Cao, S. L. Luo and B. S. Zheng*, Formation of a metal-organic framework with high gas uptakes based upon amino-decorated polyhedral cages, RSC Adv., 2015, 5, 2374-2377.
[10] B. S. Zheng*, H. Wang, Z. X. Wang*, N. Ozaki, C. Hang, X. Luo, L. Huang, W. J. Zeng, M. Yang and J. G. Duan*, A highly porous rht-type acylamide-functionalized metal-organic framework exhibiting large CO2 uptake capabilities, Chem. Commun., 2016, 52, 12988-12991.
[11] B. S. Zheng*, L. Huang,X. Y. Cao, S. H. Shen, H. F. Cao, C. Hang, W. J. Zeng and Z. X. Wang*, A highly porous acylamide decorated MOF-505 analogue exhibiting large and selective CO2 gas uptake capability, CrystEngComm, 2018, 20, 1874-1881.
[12] Z. X. Wang, X. Luo, B. S. Zheng*, L. Huang, C. Hang, Y. C. Jiao, X. Y. Cao, W. J. Zeng and R. R. Yun*, Highly selective carbon dioxide capture and cooperative catalysis of a water-stable acylamide-functionalized metal-organic framework, Eur. J. Inorg.Chem., 2018, 1309-1314.
[13] B. S. Zheng, X. Luo, Z. X. Wang*, S. W. Zhang, R. R. Yun*, L. Huang, W. J. Zeng and W. L. Liu*, An unprecedented water stable acylamide-functionalized metal-organic framework for highly efficient CH4/CO2 gas storage/separation and acid-base cooperative catalytic activity,Inorg. Chem. Front., 2018, 5, 2355-2363.
[14] R. R. Yun*, L. R. Hong, W. J. Ma, W. G. Jia, S. J. Liu* and B. S. Zheng*, Fe/Fe2O3@N-dopped porous carbon: a high-performance catalyst for selective hydrogenation of nitro compounds, ChemCatChem, 2019, 2, 724-728.
出版教材或专著:
[1] 易平贵,郑柏树主编. 物理化学实验,中国矿业大学出版社,2013年。